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Chinese "Cinnabar" and Cloisonne
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Posted by: beadiste Post Reply
07/12/2017, 10:43:48

In a recent post was mentioned the high price that eBay buyers seem to be paying for 1970s-80s Chinese cinnabar beads.
The beads that feature a combination of cloisonne and cinnabar lacquer seem to achieve especially high prices.
Invariably, it seems irresistible to sellers to described the beads as "cloisonne inlaid in lacquer."

The actual construction method is quite different - the cloisonne metal base if of course made first, as it requires high heat to melt the cloisonne enamel. Space is left for filling with lacquer later.

I purchased the pendant in the picture (I cleaned off the verdigris and black spots, it is now quite pretty), as it is an uncommon piece showing exactly how the cloisonne and lacquer are combined.

What it also shows is that the "cinnabar" seems to be a very tough type of sealing wax, not the traditional layers of tree sap lacquer. Perhaps there is some tree sap lacquer in the mix. Perhaps not. Whatever it is, it seems to be mostly wax. What kind of wax - beeswax? sealing wax? I don't have the chemical analysis skills to determine. It was poured/pressed into the space on the back of the pendant, and then carved.

What the red colorant might be is also problematic - the traditional toxic vermilion, made from mercury sulfate? Or one of the cheaper modern pigments?

Thoughts?

CloisonneCinnabarPendantA.jpg (102.6 KB)  CloisonneCinnabarPendantB.jpg (104.2 KB)  


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My Guess would be low molecular weight polyethylene, based on the waxy quality you report
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: Rosanna Post Reply
07/12/2017, 10:46:59



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Rosanna - could be something even more basic
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/12/2017, 10:49:35

This website about sealing wax is entertaining:

...sealing wax is made with several natural elements: pine resin, ground limestone, lacquer, and a dye made from cochineal -- the legendary red dye that was once one of the world’s most precious commodities.

https://www.jherbin.com/sealing_wax_fabrication.html



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Perhaps that recipe confuses shellac with lacquer?
Re: Rosanna - could be something even more basic -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/12/2017, 10:53:55

The Wikipedia article says shellac (the stuff from insects)

https://en.wikipedia.org/wiki/Sealing_wax

However, that wouldn't prevent the Chinese from having a formulation with a bit of lacquer (the stuff from trees), I guesss...

Might explain why the formulation used in beads from the 1930s appears to be susceptible to melting.



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Traditional sealing wax - possible but probably not that durable
Re: Rosanna - could be something even more basic -- beadiste Post Reply Edit Forum Where am I?
Posted by: Rosanna Post Reply
07/12/2017, 15:11:47

This formulation is interesting, but here's my thinking - that it would be expensive to assemble all the raw materials, blend the ingredients and use for an inexpensive pendant.

Plus, sealing wax is designed melt at a rather low temperature and would not be very durable for that reason.

So I'm thinking along the lines of cheap, easy to obtain polymer that will carve easily and be durable. And in the 1980s there would have been a number of polymers that would work - some type of polyethylene is just guess on my part.



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A puzzling material to test...
Re: Traditional sealing wax - possible but probably not that durable -- Rosanna Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/12/2017, 22:20:35

...because one sure wouldn't want to burn any of it to sniff the aroma of the fumes, just in case they did use vermilion.

I noticed when polishing the brass with Nevr-Dull that I had to be careful not to get the naptha product on the cinnabar, or a red wipe mark on the cloth resulted.

Guessing that means it's soluble in hydrocarbons?



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beads made from sealing wax...!
Re: A puzzling material to test... -- beadiste Post Reply Edit Forum Where am I?
Posted by: stefany Post Reply
07/13/2017, 07:50:15

but not chinese.
the 3 lots of 1900s beads at the top and centre are sealing wax, modelled hot, not unlike hot glass.
(beneath them a series of beads coated with tiny clear spheres which is another story)

sealing:wax_copy.jpg (148.3 KB)  


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Grapes pendant dates to a purchase in Hawaii circa 1980.
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/12/2017, 11:20:03

According to the seller, when queried.

The grapes design is an old-fashioned design not common in later Chinese cloisonne beads and pendants - usually one sees what appears to be a branch of blossoms, such as this doughnut pendant with sprays of flowers coming from the rock garden. This particular grapes motif appears often on cloisonne pieces from the 1920s-30s, so presumably was taught by one of the older artists to the the younger designers/workers at the Beijing Enamel Company. Grapes as a Chinese cloisonne motif go all the way back to the Ming dynasty.

I recollect a comment from a cloisonne collector that one of the tip-offs as to whether a piece was Chinese or a Japanese imitation of Chinese design was that no Chinese artist would ever feature plants without a rock or garden base. That does seem to be generally true.

CloisonnePendantStandardFlowerMotif.jpg (184.7 KB)  


Modified by beadiste at Wed, Jul 12, 2017, 11:20:50

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Is there a repair to the cinnabar near the point of the heart?
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: birdi Post Reply
07/13/2017, 05:38:56



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No repair - just the way it's carved & polished. It's supposed to be a rock.
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/13/2017, 08:12:46



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Carved lacquer has oil added - according to this research
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/13/2017, 10:27:52

Carved lacquer

It is interesting to note that Chinese craftsmen who produced carved lacquer may have taken conscious advantage of the softness and slower curing of lacquers mixed with oils. Lacquer that is to be carved must not be so hard and brittle that it is prone to chipping and breakage during carving. Because lacquer can continue to polymerize over a period of weeks and months after initial curing (Webb, 2000 Webb, M. 2000. Lacquer Technology and Conservation: A Comprehensive Guide to the Technology and Conservation of Asian and European Lacquer. Oxford: Butterworth-Heinemann.
[Google Scholar]
, p. 8), it can become progressively harder and more brittle over this timescale. From the carver's point of view then, it is critical that the prepared lacquer substrate not harden too much before the carving is complete or else the work will be ruined. It would seem that a traditional manner of preventing premature hardening has been the addition of significantly more oil to the lacquer than is customary in flat lacquer production. To date, we have only been able to analyze samples from seven objects of Chinese carved lacquer, dating from the fifteenth to eighteenth centuries. These objects include a variety of types, from Ming imperial ware to an eighteenth-century bowl from Yunnan to export ware from the southeast. Nevertheless, each of these pieces has in common a very high proportion of oil in the formulation. In most cases, the combined fatty acid peak area comprises more than 90% of the sum of all analyzed compounds while the Anacard components typically total only 3–7% of peak area. These proportions are quite unusual in flat (uncarved) lacquer that the authors have analyzed.

http://www.tandfonline.com/doi/full/10.1080/00393630.2016.1230979

[LATER: A YouTube video mentions that the lacquer tree sap is mixed with 50% oil. Tung oil seems a likely candidate to me, as it's a traditional Chinese oil.]


Related link: http://www.tandfonline.com/doi/full/10.1080/00393630.2016.1230979
Modified by beadiste at Thu, Jul 13, 2017, 16:19:49

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I was wrong - the lacquer actually is in layers, not a pressed-in paste.
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/13/2017, 13:09:25

After loupe examination I was able to see the layers.



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An eBay auction of older and more recent cinnabar beads
Re: Chinese "Cinnabar" and Cloisonne -- beadiste Post Reply Edit Forum Where am I?
Posted by: beadiste Post Reply
07/13/2017, 21:21:33

Most of the beads appear to be the style from before World War II, that show up in vintage jewelry pieces from the 1930s. Note that this is the composition sometimes referred to as "putty," that often melts or decomposes somehow. Glossy.

A few other beads show a design and dry finish that seems more post-1960s, and a cloisonne bead with waxy "cinnabar."

recent eBay auction 182666554246

Cinnabar30s80sC.jpg (136.5 KB)  Cinnabar30s80sA.jpg (117.2 KB)  


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I wish I could see the difference. Teach us.
Re: An eBay auction of older and more recent cinnabar beads -- beadiste Post Reply Edit Forum Where am I?
Posted by: birdi Post Reply
07/14/2017, 07:26:18

What are some details I should look for? I'm not seeing the difference.

I would like to know. I have cinnabar. I've rejected some that was obviously plastic or cheap. But among my modest collection, I would like to know the differences. It includes a box I bought at a swap from a Chinese man for $15. A lady in another booth frowned and insulted it. That's 2 strikes against it I suppose.

I also have beads and pendants. They used to show up in thrift stores frequently, following color trends. I bought necklaces for $3 to $7.

I sold one necklace with two-tone cinnabar beads. They were golden yellow on the outside, with red showing deep in the carving. I should have priced it higher, it sold in less than 5 minutes. Oops, should have kept that one.



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